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This textbook is devoted to the general asymptotic theory of statistical experiments. Local asymptotics for statistical models in the sense of local asymptotic (mixed) normality or local asymptotic quadraticity make up the core of the book. Numerous examples deal with classical independent and identically distributed models and with stochastic processes. The book can be read in different ways, according to possibly different mathematical preferences of the reader. One reader may focus on the statistical theory, and thus on the chapters about Gaussian shift models, mixed normal and quadratic models, and on local asymptotics where the limit model is a Gaussian shift or a mixed normal or a quadratic experiment (LAN, LAMN, LAQ). Another reader may prefer an introduction to stochastic process models where given statistical results apply, and thus concentrate on subsections or chapters on likelihood ratio processes and some diffusion type models where LAN, LAMN or LAQ occurs. Finally, readers might put together both aspects. The book is suitable for graduate students starting to work in statistics of stochastic processes, as well as for researchers interested in a precise introduction to this area.
General introduction - Definition of nanodispersions (nanosuspensions, nanoemulsions, swollen micelles or microemulsions, liposomes and vesicles) and their size range. General description of their colloid stability. Main advantages of nanodispersions and their industrial applications.Preparation of nanosuspensions by top-up process - Nucleation and growth and control of particle size distribution. Factors determining the formation of narrow particle size distribution. Role of surfactants and polymers. Preparation of nano-polymer colloids (lattices) by emulsion and dispersion polymerization. Factors affects the stability of nanosuspensions.Preparation of nanosuspensions by bottom down process - Dispersion of preformed particles in liquids and the need of a wetting agent. Break-up of aggregates and agglomerates by application of high speed stirrers. Reduction of particle size by application of intense energy (microfluidization or bead milling). Maintenance of the colloid stability of the resulting particles. Reduction of Ostwald ripening.Industrial applications of nanosuspensions - Application in pharmacy to enhance bioavailability, Application in sunscreens for UV protection. Application in paints and coatings.Preparation of nanoemulsions by the use of high pressure homogenisers - Principles of emulsion formation and the role of the emulsifier. Selection of emulsifiers. Methods of emulsification and prevention of coalescence during emulsification. Origin of colloid stability of nanoemulsions. Prevention of Ostwald ripeningLow energy methods for nanoemulsion preparation - The phase inversion composition method and the role of mixing the surfactant with oil and water. The phase inversion temperature method for preparation of nanoemulsions. Preparation of nanoemulsions by dilution of microemulsions.Practical examples of nanoemulsions and their industrial application - Nanoemulsions based on non-ionic surfactants and the role of the hydrophilic-lipophilic balance. Effect of oil solubility on the stabilityof nanoemulsions. Nanoemulsions based on polymeric surfactants. Applications in pharmacy and cosmetics.Swollen micelles or microemulsionsDefinition of microemulsions and their size range. Thermodynamic definition of microemulstions. Theories of microemulsion formation and stability. Characterisation of microemulsions using scattering, conductivity and NMR rechniques.Formulation of microemulsions and their industrial applications - Distinction between microemulsions and macroemulsions. Formulation of oil/water and water/oil microemulsions. Selection of emulsifiers for microemulsions. Application of microemulsions in tertiary oil recovery.Liposomes and vesicles - Formation of multilamellar lipid layers (liposomes) by dispersion of lipids in water. Formation of unilamellar vesicles by sonication of the liposomes. Factors responsible for stabilisation of liposomes and vesicles. Use of block copolymers to enhance the stability of vesicles. Applications of liposomes and vesicles in pharmacy and cosmetics.
Along with the first volume on "e;Industrial Chemistry"e; this book discusses, illustrates and explains many of the major chemical processes performed by industry, looks at how transformations affect the quality of our lives, examines the various types of waste produced as necessary products are developed and marketed, and shows techniques and practices in which many industries have made strides to improve or "e;green"e; specific chemical processes.
This book is an introduction to nonlinear programming. It deals with the theoretical foundations and solution methods, beginning with the classical procedures and reaching up to "e;modern"e; methods like trust region methods or procedures for nonlinear and global optimization. A comprehensive bibliography including diverse web sites with information about nonlinear programming, in particular software, is presented. Without sacrificing the necessary mathematical rigor, excessive formalisms are avoided. Several examples, exercises with detailed solutions, and applications are provided, making the text adequate for individual studies. The book is written for students from the fields of applied mathematics, engineering, economy, and computation.
Nanoparticles presents the remarkable variety of nanoparticle families, compositions, structures, and functions. The book discusses nanoparticles made of semiconductors, metals, metal-oxides, organics, biological and hybrid constituents.Through a wealth of examples and case studies, supplemented by numerousfigures, readers that are not necessarily active or experts in this area acquire abroad overview of this exciting field at the interface between scientifi c research and practical technologies.The contents summarize the contributions to this field of diverse scientific and technological disciplines- chemistry, physics, biology, electronics and others providing acomprehensive knowledge- the types of nanoparticles, their compositions and how the relationships between the atomic constituents affect their properties, as well as potential applications of nanoparticles.- Covers diverse uses of nanoparticles in scientifi c research and industrial applications, underscoring their extraordinary diversity and potential utilization.- Experimental and conceptual approaches applied to the study of nanoparticles are discussed extensively. Additional references provide the reader with a basis for further study.- Also available by Professor Jelinek: Biomimetics - A Molecular Perspective (2013), ISBN: 978-3-11-028117-0
Industrial Inorganic Chemistry adds to the previously published graduate level textbooks on Industrial Chemistry by Mark A. Benvenuto. It focuses specifically on inorganic processes, from the largest industrial process for the production of major inorganic chemicals and metals, down to and including smaller niche processes that have become extremely important in maintaining the current quality of life. The book provides a survey on the production of essential elements and compounds, such as sulfuric acid, calcium carbonate, fertilizers as well as numerous metals and alloys. In addition to the fundamental scientific principles each chapter includes discussions on the environmental impacts: mining of raw materials, creation of by-products, pollution, and waste generation, all of which have become key factors for the potential implementation of greener methods. The author also highlights ways in which industry has begun to make industrial inorganic processes more environmentally benign. Examines major inorganic chemistry processes, their effect on every-day life and current efforts to improve processes or adapt green"e; chemical production. Provides didactic links between theoretical lecture contents and current, largescale chemical processes. Valuable for students of Inorganic Chemistry, Industrial Chemistry, Chemical Engineering and Materials Sciences.
Cryptography has become essential as bank transactions, credit card infor-mation, contracts, and sensitive medical information are sent through inse-cure channels. This book is concerned with the mathematical, especially algebraic, aspects of cryptography. It grew out of many courses presented by the authors over the past twenty years at various universities and covers a wide range of topics in mathematical cryptography. It is primarily geared towards graduate students and advanced undergraduates in mathematics and computer science, but may also be of interest to researchers in the area. Besides the classical methods of symmetric and private key encryption, the book treats the mathematics of cryptographic protocols and several unique topics such as Group-Based Cryptography Grobner Basis Methods in Cryptography Lattice-Based Cryptography
This two-volume graduate textbook gives a comprehensive, state-of-the-art account of describing large subgroups of the unit group of the integral group ring of a finite group and, more generally, of the unit group of an order in a finite dimensional semisimple rational algebra. Since the book is addressed to graduate students as well as young researchers, all required background on these diverse areas, both old and new, is included. Supporting problems illustrate the results and complete some of the proofs. Volume 1 contains all the details on describing generic constructions of units and the subgroup they generate. Volume 2 mainly is about structure theorems and geometric methods. Without being encyclopaedic, all main results and techniques used to achieve these results are included. Basic courses in group theory, ring theory and field theory are assumed as background.
Signals and systems enjoy wide application in industry and daily life, and understanding basic concepts of the subject area is of importance to undergraduates majoring in engineering. With rigorous mathematical deduction, this introductory text book is helpful for students who study communications engineering, electrical and electronic engineering, and control engineering. Additionally, supplementary materials are provided for self-learners.
This two-volume graduate textbook gives a comprehensive, state-of-the-art account of describing large subgroups of the unit group of the integral group ring of a finite group and, more generally, of the unit group of an order in a finite dimensional semisimple rational algebra. Since the book is addressed to graduate students as well as young researchers, all required background on these diverse areas, both old and new, is included. Supporting problems illustrate the results and complete some of the proofs. Volume 1 contains all the details on describing generic constructions of units and the subgroup they generate. Volume 2 mainly is about structure theorems and geometric methods. Without being encyclopaedic, all main results and techniques used to achieve these results are included. Basic courses in group theory, ring theory and field theory are assumed as background.
This textbook on functional analysis offers a short and concise introduction to the subject. The book is designed in such a way as to provide a smooth transition between elementary and advanced topics and its modular structure allows for an easy assimilation of the content. Starting from a dedicated chapter on the axiom of choice, subsequent chapters cover Hilbert spaces, linear operators, functionals and duality, Fourier series, Fourier transform, the fixed point theorem, Baire categories, the uniform bounded principle, the open mapping theorem, the closed graph theorem, the Hahn-Banach theorem, adjoint operators, weak topologies and reflexivity, operators in Hilbert spaces, spectral theory of operators in Hilbert spaces, and compactness. Each chapter ends with workable problems.The book is suitable for graduate students, but also for advanced undergraduates, in mathematics and physics. Contents:List of FiguresBasic NotationChoice PrinciplesHilbert SpacesCompleteness, Completion and DimensionLinear OperatorsFunctionals and Dual SpacesFourier SeriesFourier TransformFixed Point TheoremBaire Category TheoremUniform Boundedness PrincipleOpen Mapping TheoremClosed Graph TheoremHahn-Banach TheoremThe Adjoint OperatorWeak Topologies and ReflexivityOperators in Hilbert SpacesSpectral Theory of Operators on Hilbert SpacesCompactnessBibliographyIndex
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