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Organometallic compounds are utilized as reagents in the preparation and processing of advanced nanostructured materials, as catalysts in the production of a variety of specialty chemicals and polymers, and as drugs. This book covers the fundamental aspects and related applications in this rapidly growing area.
Provides an introduction to supercritical fluids with easy-to-use Excel spreadsheets suitable for both specialized-discipline (chemistry or chemical engineering student) and mixed-discipline (engineering/economic student) classes. In this book, each chapter contains worked examples, tip boxes and end-of-the-chapter problems and projects.
Hydrothermal and Supercritical Water Processes presents an overview on the properties and applications of water at elevated temperatures and pressures. It combines fundamentals with production process aspects. Water is an extraordinary substance. At elevated temperatures (and pressures) its properties change dramatically due to the modifications of the molecular structure of bulk water that varies from a stable three-dimensional network, formed by hydrogen bonds at low and moderate temperatures, to an assembly of separated polar water molecules at high and supercritical temperatures. With varying pressure and temperature, water is turned from a solvent for ionic species to a solvent for polar and non-polar substances. This variability and an enhanced reactivity of water have led to many practical applications and to even more research activities, related to such areas as energy transfer, extraction of functional molecules, unique chemical reactions, biomass conversion and fuel materials processing, destruction of dangerous compounds and recycling of useful ones, growth of monolithic crystals, and preparation of metallic nanoparticles. This book provides an introduction into the wide range of activities that are possible in aqueous mixtures. It is organized to facilitate understanding of the main features, outlines the main applications, and gives access to further information
Particle formation with supercritical fluids is a promising alternative to conventional precipitation processes as it allows the reduction of particle size and control of morphology and particle size distribution without degradation or contamination of the product. The book comprehensively examines the current status of research and development and provides perspectives and insights on promising future directions. . The introduction to high pressure and high temperature phase equilibria and nucleation phenomena provides the basic principles of the underlying physical and chemical phenomena,allowing the reader an understanding of the relationship between process conditions and particle characteristics. . Bridging the gap between theory and application, the book imparts the scientific and engineering fundamentals for innovative particle formation processes. The interdisciplinary "modus operandi" will encourage cooperation between scientists and researchers from different but complementary disciplines.
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